Document Type

Article

Publication Date

12-2003

Scholarship Domain(s)

Scholarship of Discovery

Abstract

New quaternary ammonium salts that contain polyfluorinated alkyl substituents were prepared by the polyfluoroalkylation of tertiary amines with polyfluorinated alkyl iodides. Metathesis reactions of the iodide salts with fluorine-containing anions resulted in new low melting salts. The iodide salts of the tri(isooctyl)polyfluoroalkyl amines are also liquids at 25°C.

Comments

Author's post-print of article accepted for publication in Tetrahedron Letters (Pergamon) in September 2003.

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